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한국폐기물자원순환학회> 한국폐기물자원순환학회지> 해양 (미세)플라스틱이 기후인자에 미치는 영향에 관한 고찰

KCI등재

해양 (미세)플라스틱이 기후인자에 미치는 영향에 관한 고찰

Consideration on the Effect of Marine (micro)Plastics on the Climatic Factor

김용진 ( Yong-jin Kim ) , 이혜성 ( Hye-sung Lee )
  • : 한국폐기물자원순환학회
  • : 한국폐기물자원순환학회지 38권5호
  • : 연속간행물
  • : 2021년 10월
  • : 377-386(10pages)
한국폐기물자원순환학회지

DOI

10.9786/kswm.2021.38.5.377


목차

I. 서 론
II. 해양 (미세)플라스틱이 기후변화에 미치는 영향
III. 요약 및 향후 과제
사 사
References

키워드 보기


초록 보기

Although the effects of marine microplastics on living organisms and their roles as carriers of organic pollutants to living organisms and the marine environment have already been studied, this paper focuses on the effects of marine microplastics on climate that haven’t been studied yet. Microplastics in the oceans absorb more solar radiation and alter the biophysical properties of the surface microlayer, resulting in an increase in the sea surface temperature (SST). An increase in the SST and the concentration of microplastics that cover the surface layer, interrupts the physical interaction between seawater and carbon dioxide (CO2) in the atmosphere. Consequently, the solubility of carbon dioxide in seawater is lowered, and thereby increases the retention time of CO2 in the atmosphere. Furthermore, plastics that are in the ocean can be decomposed by solar radiation, such as UV-B rays and directly release greenhouse gases such as methane, ethylene, ethane, and propylene, and thereby accelerates the greenhouse effect. Therefore, considering the marine microplastics as a new factor in the ocean- atmosphere coupled model, the extent of the impact of microplastics on weather should be quantitatively reviewed.

UCI(KEPA)

I410-ECN-0102-2022-500-000907747

간행물정보

  • : 공학분야  > 환경공학
  • : KCI등재
  • :
  • : 격월
  • : 2093-2332
  • : 2287-5638
  • : 학술지
  • : 연속간행물
  • : 1984-2022
  • : 2983


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1폐기물매립지의 메탄 배출량 측정 정확도 향상을 위한 시·공간적 배출 특성 고찰

저자 : 송상훈 ( Sang-hoon Song ) , 김란희 ( Ran-hui Kim ) , 이남훈 ( Nam-hoon Lee ) , 박진규 ( Jin-kyu Park )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 39권 6호 발행 연도 : 2022 페이지 : pp. 477-488 (12 pages)

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First-order decay models have been used to estimate annual landfill methane emissions for national greenhouse gas inventories. These models vary greatly. Inaccurate input values or oversimplified processes, such as methane oxidation or dynamic methane emission rates, cause this downside. Direct field measurements can be used to predict total methane emissions more accurately. Methane emission rates fluctuate weekly and daily and are influenced by the soil cover and meteorological conditions such as barometric pressure, temperature, rain, and wind speed. Hotspot emissions contribute significantly to landfill methane emissions. To accurately estimate annual methane emissions, direct field measurements must account for meteorological effects and quantify hotspot emissions during landfill emission monitoring programs. In South Korea, there are no field-based calculations, hampering the development of a strategic strategy to reduce methane emissions from solid waste landfills. South Korea must develop innovative methods to quantify landfill methane emissions and a mitigation strategy.

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2수출·입 폐기물의 관리 개선 마련 연구: 관세·통계통합품목분류표(HSK)를 중심으로

저자 : 박윤수 ( Yoon Soo Park ) , 전태완 ( Tae-wan Jeon ) , 신선경 ( Sun-kyoung Shin ) , 엄남일 ( Nam-il Um )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 39권 6호 발행 연도 : 2022 페이지 : pp. 489-497 (9 pages)

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The export and import waste generated in Korea amounts to 2.63 million tons per year (about 4% of total industrial waste). During importing and exporting waste, an item code called the Harmonized System of Korea (HSK) is assigned to it through classification, inspection, and customs clearance procedures. This study prepared methods for identifying the current status of HSK, systematizing HSK, and effectively applying HSK. First, the following were investigated: the status of the HSK Code, the current status of HSK management in Korea, and HSK related to waste. As a result, Korea adopted the HSK classification table and operated with it as a notice by the Ministry of Economy and Finance. A system of 10 units is used, and there are about 339 HSK related to waste. Second, it was found that there were wastes without HSK or that some items did not match. 119 new HSK were proposed for 17 types of imported and exported waste. Third, it was found that, at times, responsible personnel made the wrong decision or intentionally entered incorrect HSK in the process of importing and exporting waste. Designated and ordinary industrial wastes under the “Waste Control Act” of Korea need to be linked with the HSK.

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3우리나라 폐기물매립지 온실가스 감축방안 : 매립가스 유효활용의 발전 및 과제

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발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 39권 6호 발행 연도 : 2022 페이지 : pp. 498-509 (12 pages)

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South Korea's most recent national inventory report found that landfills are the largest anthropogenic source of methane. Despite decades of closure, landfill methane emissions threaten human health and climate change. This study investigates landfill gas (LFG) valorization to reduce these emissions. This technique converts LFG into value-added chemicals like biomethane, syngas (a mixture of carbon monoxide and hydrogen), methanol, and dimethyl ether. LFG valorization is an interesting approach to mitigate greenhouse gas emissions and shift toward a low-carbon society, but it is not economically feasible. To reduce carbon emissions and boost LFG valorization in South Korea, a carbon tax and/or subsidies may be considered. Establishing a sustainable LFG valorization technology would provide enough momentum to create a circular carbon-based economy.

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4전과정평가 기법을 활용한 커피박 자원화의 환경부하 저감효과 분석 : 일반합성목재와 커피박합성목재의 환경영향 비교를 중심으로

저자 : 이종효 ( Jong Hyo Lee ) , 황용우 ( Yong Woo Hwang ) , 황윤수 ( Youn Soo Hwang )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 39권 6호 발행 연도 : 2022 페이지 : pp. 510-520 (11 pages)

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In this study, we compare the environmental loads of the coffee waste wooden deck and the general wooden deck using the life cycle assessment (LCA). We estimate the coffee waste wooden deck's environmental advantages by LCA methodology. According to our findings, a coffee waste wooden deck reduces environmental load by 13.2% when compared to a general wooden deck. The reduction ratio for eutrophication potential was 20.4%, acidification potential was 19.4%, and global warming potential was 15.9%. Among the six environmental impact categories, abiotic depletion had the least reduction. In particular, while CO2 emission reduction may seem insignificant numerically from the functional unit's perspective, it can be considered a significant reduction effect given the characteristics of building materials. Assuming the trail construction, which has 3.6 m of width and 360 m of length (1,320 m2), the reduction effect of the environmental load is approximately 11.6 ton CO2-eq. Moreover, it reduces environmental load by 11.6 tons of CO2 equivalent per year and absorbs as much GHGs as 4,936 pine trees or 3,277 oak trees. This study helps management and policymakers visualize the impact of recycling coffee waste on the environment.

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저자 : 엄희숙 ( Hee Suk Eom ) , 전병준 ( Byung Jun Jeon ) , 신동훈 ( Donghoon Shin )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 39권 6호 발행 연도 : 2022 페이지 : pp. 521-531 (11 pages)

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Biochar is a charcoal-like material that separates and stores the carbon component of organic biomass that is grown by absorbing the greenhouse gas emissions produced from burning fuel. Interestingly, when biochar is used as an additive during mortar production, the effect of the stored greenhouse gas is evident in the characteristics of the building. In this study, we experimentally evaluate the bending strength of mortar when biochar partially replaces the content of sand in mortar production. Under the condition that the ratio of cement to sand is 1: 3, in the range of 0% to 9.3% based on the mass of cement, we produce specimens in which some sand had been replaced with biochar in 4 cm × 16 cm × 1 cm. Following this, the bending strength of these specimens is measured using a three-point bending strength-measuring device at 7 days and 28 days respectively. Our findings reveal that at up to 7% of biochar replacement rate, it is possible to produce a greenhouse gas-stored mortar without loss of mortar strength; more so, we observed that the 5% biochar replacement rate demonstrates the highest bending strength showing that the advantage of strength improvement can also be utilized.

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6파일럿 스케일 버너에서 바이오 중유 및 바이오 원유 혼합연료의 연소 특성

저자 : 정연우 ( Yeonwoo Jeong ) , 류영현 ( Younghyun Ryu ) , 최상규 ( Sangkyu Choi ) , 최연석 ( Yeonseok Choi ) , 한소영 ( Soyoung Han ) , 응웬반꾸잉 ( Quynhvan Nguyen )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 39권 6호 발행 연도 : 2022 페이지 : pp. 532-542 (11 pages)

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Carbon neutrality is a balance between emitting carbon and absorbing carbon from the soil, forest, and oceans. To achieve carbon neutrality by 2050, a variety of research on energy such as solar, wind, hydrogen, biomass, and waste energy has been performed worldwide. Bio-fuel oil and bio-crude oil are considered promising energy resources to achieve carbon neutrality because they can be effectively used not only for heat energy but also for transport fuel. In this study, an experiment on the combustion characteristics of bio-fuel oil and bio-crude oil blends was conducted. The mixtures of biofuel and conventional diesel fuel were also studied. A conventional oil burner with a 35 kW capacity was modified into a downward injection type and to adopt an air-blast atomizing nozzle. Bio-fuel oil was made from waste oil and bio-crude oil was derived from coffee grounds. The temperature distributions in the combustion chamber and the gaseous emissions were compared at various blending ratios. When the bio-fuel oil was blended with bio-crude oil from the coffee ground, nearly complete combustion was observed, except for the 100% bio-crude oil, with the emission of a large amount of CO. It was also shown that as the ratio of bio-crude oil was increased, NO concentration increased due to the nitrogen content in the bio-crude oil. In the cases where biofuel was blended with diesel fuel, all cases showed close to complete combustion, where the temperature of the combustion chamber was raised with an increasing ratio of diesel.

KCI등재

7Powder-Type 산화칼슘(CaO)을 이용한 육불화황(SF6) 분해 부산물의 고정화 연구

저자 : 류재용 ( Jae Yong Ryu )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 39권 6호 발행 연도 : 2022 페이지 : pp. 543-552 (10 pages)

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Climate change represents a worldwide warning on global warming and has elevated awareness on the global climate crisis. As a result, worldwide changes to tackle climate change have been initiated. In compliance with the Paris agreement, Korea has declared Carbon Net Zero and implemented legislative changes. Regarding the greenhouse gas emissions in Korea, the mineral industry plays a large role among other industries. A huge amount of greenhouse gases is emitted during the decarboxylation and calcination processes in the cement production process. Therefore, to address the climate crisis, the cement industry also needs to develop technologies to promote carbon neutrality. This study was conducted to explore ways to control SF6, of which GWP is the highest, using cement kiln and thermal plasma, and to recycle the byproduct of pyrolysis into an eco-friendly cement supplementary material by immobilizing it with calcium oxide. The destruction and removal efficiency of SF6 was 100%, while the immobilization reaction rate calculated from the concentration change of the by-product was 99.4%. As a by-product of the immobilization reaction, cement subsidiary raw materials such as fluorite (CaF2) and anhydrite (CaSO4) were generated, and it is thought that recycling of these raw materials is possible.

KCI등재

8폐자원에너지 시설의 환경성 및 경제성 평가에 따른 지원방안 연구

저자 : 박세인 ( Se-in Park ) , 이유민 ( Youmin Lee ) , 남궁훤 ( Hueon Namkung ) , 강준구 ( Jun-gu Kang ) , 전태완 ( Taewan Jeon )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 39권 6호 발행 연도 : 2022 페이지 : pp. 553-561 (9 pages)

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Although the need for new and renewable energy is increasing, support for waste-to-energy facilities has been reduced as the related laws have been amended. Accordingly, there are concerns about the weakening of the competitiveness of waste-to-energy facilities. Therefore, this research conducted a study on the support methodology for waste-to-energy facilities. To provide support for waste-to-energy facilities, it is necessary to evaluate the related facilities based on common factors. In this study, for the evaluation of waste-to-energy facilities, the environmental indicator was calculated by using the environmental properties of the facility as a factor, while the benefit calculated by examining the energy production of the waste-to-energy facility was used as the economic indicator. In addition, the numerical values of each indicator were simplified through normalization, and the scores of the environmental and economic indicators were calculated by scoring the normalized values. For the calculated result, the sum of the environmental and economical scores was used as the overall score of the facility by applying the indicator reflection ratio.

KCI등재

9코로나 19 고발열 의료폐기물이 소각시설 대기오염물질 배출특성에 미치는 영향

저자 : 이은송 ( Eunsong Lee ) , 김진태 ( Jintae Kim ) , 이정규 ( Jungyu Lee ) , 신완호 ( Wanho Shin ) , 한소영 ( Soyoung Han ) , 홍원석 ( Wonseok Hong ) , 윤진한 ( Jinhan Yun )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 39권 6호 발행 연도 : 2022 페이지 : pp. 562-571 (10 pages)

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This study evaluated the effect of the COVID-19 pandemic on nitrogen oxides emissions from a medical waste incinerator. During the summer vacation season and year-end periods, the amount of medical waste as well as COVID- 19 patients dramatically increased by 2 to 6 times. In addition, nitrogen oxide emissions increased by approximately 30 % due to the injection of high calorific medical waste into the medical waste incinerator. The increase in medical waste calorific value is attributed to the exclusion of diapers from the medical waste classification and the composition of synthetic resins in waste transport containers. By applying the energy conservation law, the estimated waste calorific value for the months with the highest and lowest nitrogen oxides emissions were ~5,250 kcal/kg and 4,760 kcal/kg, respectively. The correlation between waste calorific value and nitrogen oxide was confirmed. However, the calorific value of medical waste varies for each transport container, and there is a limit in constantly controlling the calorific value of the injected waste. Therefore, to minimize the environmental impact of medical waste incinerators, it is necessary to apply combustion optimization technologies such as flue gas recirculation and air staging combustion to control air pollution.

KCI등재

10천연 가죽 폐기물을 이용한 가스켓 시트 제조에서 가죽 폐기물 및 실리카 충진제별 물성 변화 연구

저자 : 정득준 ( Deukjun Jeong ) , 김관용 ( Gwanyong Kim ) , 이상철 ( Sangchul Lee )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 39권 6호 발행 연도 : 2022 페이지 : pp. 572-579 (8 pages)

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This study is on an upcycle technology for manufacturing gasket sheets using solid waste generated in the manufacturing process of natural leather. Regarding the manufacturing of rubber gasket sheets based on dry manufacturing technology, we studied the crosslinking characteristics and mechanical characteristics of shaving scrap and trimming scrap according to the types of natural leather waste, where the effect of the type of silica used as a reinforcing filler was investigated. As a result, research on industrial recycling items that reduce carbon usage and do not generate wastewater was conducted.

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1해양 (미세)플라스틱이 기후인자에 미치는 영향에 관한 고찰

저자 : 김용진 ( Yong-jin Kim ) , 이혜성 ( Hye-sung Lee )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 38권 5호 발행 연도 : 2021 페이지 : pp. 377-386 (10 pages)

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Although the effects of marine microplastics on living organisms and their roles as carriers of organic pollutants to living organisms and the marine environment have already been studied, this paper focuses on the effects of marine microplastics on climate that haven't been studied yet. Microplastics in the oceans absorb more solar radiation and alter the biophysical properties of the surface microlayer, resulting in an increase in the sea surface temperature (SST). An increase in the SST and the concentration of microplastics that cover the surface layer, interrupts the physical interaction between seawater and carbon dioxide (CO2) in the atmosphere. Consequently, the solubility of carbon dioxide in seawater is lowered, and thereby increases the retention time of CO2 in the atmosphere. Furthermore, plastics that are in the ocean can be decomposed by solar radiation, such as UV-B rays and directly release greenhouse gases such as methane, ethylene, ethane, and propylene, and thereby accelerates the greenhouse effect. Therefore, considering the marine microplastics as a new factor in the ocean- atmosphere coupled model, the extent of the impact of microplastics on weather should be quantitatively reviewed.

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2피혁 폐기물 업사이클링 기술에 기반한 친환경 건축용 텍스 소재 개발 연구

저자 : 이상철 ( Sang-chul Lee ) , 김관용 ( Gwan-yong Kim ) , 정득준 ( Deuk-jun Jung )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 38권 5호 발행 연도 : 2021 페이지 : pp. 387-394 (8 pages)

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This study investigated the use of leather shaving scraps, which is inevitably produced during leather processing, in an upcycling technology. Particularly, this study investigated the development of eco-friendly ceiling panels material as alternatives to currently used built-in gypsum ceiling panels for building construction. Existing gypsum ceiling panels exhibit very poor moisture absorption characteristics, which increase the cost of raw materials during the manufacturing process. In addition, exposure to radon, which is present in the raw materials used for the manufacturing of phosphoric acid gypsum, poses hazardous risks to the human body, such as lung cancer and stomach cancer. Moreover, the release these raw materials into the environment results in secondary pollution in high-moisture environment, as these materials facilitate the growth of fungi. Furthermore, gypsum ceiling panels exhibit a poor durability owing to their weak impact strength. In addition, the high production cost of gypsum has restricted its continuous mass production for building construction materials. To address these problems, this study employed a pulverization process to mix, cross-link, and vulcanize leather waste and rubber to fabricate ceiling panels materials for building construction using a dry method. The fabricated panel materials exhibited good strength, flame retardancy, waterproofness, and radon-free properties. The upcycling technology proposed in this study is an eco-friendly, halogen-free method that utilizes leather waste as the main raw material and aluminum hydroxide as a flame retardant. The cross-linking characteristics of the material with a change in the filler and cross-linking system were analyzed. In addition, the manufacturing characteristics and physical properties of the ceiling panels with a change in the flame retardants were investigated. The results revealed that the manufactured ceiling panels with the optimal formulation satisfied the UL-94 standard, and exhibited a hardness of 55 D and density of 1.339.

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발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 38권 5호 발행 연도 : 2021 페이지 : pp. 395-404 (10 pages)

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This study investigated the optimal reaction condition for the production of hydrogen from the steam reforming of mixed alkane hydrocarbons using thermodynamic analysis. C1-C4 alkane hydrocarbons (CH4, C2H6, C3H8, and C4H10) were utilized as the reactants in the thermodynamic equilibrium analysis using Gibbs free energy minimization. The equilibrium composition, CH4 moles, CH4 conversion, selectivity (CO, CO2, C, and CH4), and H2 moles were estimated at various temperatures (200-1,000℃) and H2O/C ratios (0.5-3.0). The steam reforming of mixed alkane hydrocarbons is a complex reaction that proceeds simultaneously with the cracking of C2-C4, carbon formation, steam reforming, and water gas shift reactions. In addition, the results revealed that the reaction temperature and H2O/C ratio are important factors for these reactions. Furthermore, the reaction temperature and H2O/C ratio had no significant effect on the decomposition of C2-C4 alkanes (i.e., C2H6, C3H8, and C4H10), as they were totally converted into CH4 at temperatures below 650℃. In contrast, the H2O/C ratio had a significant effect on the carbon formation, as carbon formation did not proceed at H2O ratios of 2.0 and above. In addition, carbon was primarily produced in the temperature range from 350-550℃. Furthermore, the steam reforming reaction of CH4 dominantly occurred at a high temperature (>650℃) and H2O/C ratio (>1.5). In addition, high H2O/C ratios favored the water gas shift reaction, which could be attributed to the presence of excess H2O. The inhibition of cracking and coke formation and the maximization of the steam reforming and water gas shift reactions were considered for the stable operation of the process and production of hydrogen. The results revealed that the optimum temperature and H2O/C ratio for achieving a high CH4 conversion (>80%) and H2 moles (>25 mol) were ≥700℃ and >2.0, respectively.

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4수열탄화를 통한 축분의 연료특성 및 소수성 개선 연구

저자 : 장은석 ( Eun-suk Jang ) , 김대기 ( Daegi Kim )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 38권 5호 발행 연도 : 2021 페이지 : pp. 405-411 (7 pages)

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In this study, livestock manure was converted into fuel using hydrothermal carbonization, and the chemical composition of the resulting fuel was investigated. The results revealed that the hydrogen and oxygen content of the resulting fuel decreased, whereas the carbon content increased. In addition, there was a reduction in nitrogen content, which could be attributed to the gradual reduction in potential NOx emission, and the decomposition of organic nitrogen under thermal reaction conditions to liquid and gas. Furthermore, the hydrothermal carbonization removed some of the volatile matter in the manure and increased the proportion of fixed carbon content; thus, resulting in an increase in fuel ratio from 0.32 to 0.68 with an increase in the reaction temperature. These results indicated that the calorific value increased after hydrothermal carbonization. However, at hydrothermal carbonization temperatures above 250℃, the formed products exhibited a high ash content of 36.07- 41.54%, which had no effect on the increase in the calorific value. The storage and stability of the biomass fuel was investigated using a moisture reabsorption experiment. There was a sharp decrease in the moisture reabsorption value of the fuel, and only 75% of the raw reabsorption value was retained. This could be attributed to the removal of hydrophilic groups, such as OH (hydroxyl group) and C=O (carboxyl group), from the manure by the hydrothermal carbonization process.

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5폐기물의 시멘트 소성로 대체 연료 활용 확대를 위한 분석 표준운영절차(안) 도출

저자 : 한건호 ( Gun Ho Han ) , 기동원 ( Dongwon Ki ) , 강신영 ( Shin Young Kang ) , 오대성 ( Dae Sung Oh ) , 김명기 ( Myoung Kee Kim ) , 박세원 ( Se Won Park )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 38권 5호 발행 연도 : 2021 페이지 : pp. 412-425 (14 pages)

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Since the 1970s, waste tires have been used as auxiliary fuel in Korea, and the Korean cement industry has employed various wastes as auxiliary fuels and alternative materials. The main fuels used in cement kiln are bituminous coal and coke, and as of 2018, the rate of waste tires used as auxiliary fuel in Korea was only 23% (based on the heating value by the fossil fuel). This value was almost half of that of Europe (46%) and one-third of that of Germany (68%). Owing to the high temperature conditions of the gas and solid (materials) in cement kilns (2,000 and 1,450°C, respectively), most harmful pollutants, such as heavy metals, are volatilized; thus, eliminating the environmental impact of waste fuel. However, the use of waste fuel and materials in cement production process has garnered the negative perceptions of people. To address this problem, the Korean government and cement industry established the “Waste Use and Management Standard for Cement Kilns” in 2009; however, this had no significant effect on the negative perceptions of the people. The effective disposal of waste in Korea has remained a challenge owing to lack of additional landfill areas and incinerators; particularly, China's ban on waste imports in April 2018 has compounded this problem. To actively utilize combustible waste as alternative fuels for cement production process, this study proposed thermal/environmental and quality/environmental analysis candidates and standards, and suggested a standard operating procedure for cement kilns. The standard operating procedure of waste proposed in this study included heating value, elementary, and heavy metals content analyses, and that of cement included physical and chemical composition, heavy metals content and leaching, and radioactivity analyses. We believe that the proposed standard operating procedure can be employed in the future to ensure the reliability and enhancement of the utilization of waste as alternative fuels for cement production. Additionally, the standard proposed in this study may solve problems related to domestic waste disposal.

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6바이오가스 적용 캐비티 매트릭스 연소기 개발

저자 : 안준 ( June An ) , 김하진 ( Ha Jin Kim ) , 전영남 ( Young Nam Chun )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 38권 5호 발행 연도 : 2021 페이지 : pp. 426-433 (8 pages)

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The effects of conventional fossil fuels on the environment, such as air and carbon pollutions, have limited their use as an energy resource. To address this problem, biogas has emerged as an alternative energy source owing to its sustainable and renewable characteristics. In this study, we proposed a new type of cavity matrix combustor that can directly burn the products of small and medium-sized biogas facilities without the use of complicated facilities, such as CO2 separation or purification facilities. To identify the combustion characteristics of the cavity matrix combustor, parametric screening studies were conducted based on changes in air ratio, total gas supply, biogas composition, and exhaust recirculation, and the optimal operating conditions were suggested based on the results. The performance test of the cavity matrix combustor revealed that the combustor exhibited excellent biogas combustion characteristics. In addition, the optimal operating air ratio and total gas supply conditions at which the combustor exhibited a combustion efficiency of 79.2% for a biogas composed of 60% CH4 and 40% CO2 were 1.1 and 30 L/min, respectively. Furthermore, the content of CO and UHCs, which were unburned gases, in the combustor were 0.03 and 0.01%, respectively, and that of NOx was 1 ppm. In addition, the combustion efficiency of the combustor slightly increased to 86.59% when combustion gas recirculation was performed.

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7금-은 폐광산 광미의 수은 열적감량 특성

저자 : 조수진 ( Soo-jin Cho ) , 서용칠 ( Yong-chil Seo ) , 이은송 ( Eun-song Lee ) , 고주인 ( Ju-In Ko )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 38권 5호 발행 연도 : 2021 페이지 : pp. 434-441 (8 pages)

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This study conducted thermal desorption experiments for the remediation of mercury-contaminated soils with a mercury concentration of 26.39 mg-Hg/kg from gold-silver mine tailings. The thermal desorption experiments were performed in a muffle furnace at a pressure of 1 atm in the temperature range from 300 to 700℃. In addition, indirect thermal treatment experiments were conducted by adding 20 g of homogeneous samples into the crucible for 1 to 30 min. The mercury concentrations of the residual samples were analyzed using EPA method 7471a. Based on the results of the analysis of mercury concentration in the thermal treatment, the thermal desorption characteristics of mercury contaminated tailings were analyzed using reaction rate theory. The reaction rate constants (k) were calculated from 1.3 × 10-3 to 1.9 × 10-2 sec-1 with a change in the temperature conditions. The results revealed that k increased with increasing temperature. In addition, the calculated pre-exponential factor and activation energy were 0.118 sec-1 and 2.76 kcal/gmol, respectively. Furthermore, the thermal treatment conditions required to achieve the 4 mg-Hg/kg criteria for Hg content were approximately 1,451 s at 300℃ and 992 s at 400℃.

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8계층화 분석을 이용한 공공건축물의 순환골재 활용 활성화 요인 분석

저자 : 이두길 ( Doo Gil Lee ) , 박성용 ( Seong Yong Park ) , 이상조 ( Sang Jo Lee ) , 정재우 ( Jae Woo Chung )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 38권 5호 발행 연도 : 2021 페이지 : pp. 442-451 (10 pages)

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This study employed the analytic hierarchy process (AHP) to investigate the main decision-making factors involved in the selection of materials forrecycled aggregates for constructing public buildings. The factors, which consisted of five main items and 15 detailed items in the AHP model, were devised through consultations with construction experts. Based on the weights of the main and detailed items, the “Subject to mandatory use” element exhibited the highest level of importance, followed by the “supplier” and “price” elements in the procurement sector, and the “specification content” in the construction sector. Furthermore, the results revealed that it is essential to reflect the use of recycled aggregates at the initial design stage and to introduce a mandatory use of recycled aggregates. In addition, the criteria for suppliers to meet upgrading the production technology of recycled aggregates are required.

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9탈취제 성상에 따른 슬러지 내 황화수소 저감에 관한 연구

저자 : 정회석 ( Hoesuk Jung ) , 이수정 ( Sujeong Lee ) , 선제호 ( Jeaho Seon ) , 요스케카츠라 ( Yousuke Katsura ) , 한인섭 ( Ihnsup Han )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 38권 5호 발행 연도 : 2021 페이지 : pp. 452-457 (6 pages)

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This study compared H2S removal efficiency of two types of deodorants (NOx deodorant ACE and Fe3+ deodorant S) at high temperature versus low temperature (summer/winter). For both temperature conditions, NOx deodorant ACE removed H2S by 99% or more within 2 hours at the least dose of 2.5% (w/w), and this lasted for about 8 hours maximum. Fe3+ deodorant S removed H2S by 99% or more at the dose of 5.0% (w/w), and this lasted for about 6 hours maximum. For the sludge where H2S exists at high concentration, NOx deodorant ACE was the most appropriate. For Fe3+ deodorant S, additional alkaline chemicals are expected to be necessary.

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10Study of Bio-Waste Anaerobic Digestion and its Membrane Purification Technologies in Oversea: I. Malaysian Biogas Scale-up Case

저자 : 박영규 ( Young Gyu Park ) , 선영근 ( Young Geun Sun )

발행기관 : 한국폐기물자원순환학회 간행물 : 한국폐기물자원순환학회지 38권 5호 발행 연도 : 2021 페이지 : pp. 458-472 (15 pages)

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The palm oil mill industry in Malaysian generates 100 million ton of palm oil mill effluent (POME) and EFB (empty fruit bunch) as byproducts annually. This study identified the location, capacity and technology of biogas refinery plants for the production of biogas from the byproducts of the Malaysian palm oil mill plant. This study investigated the production of biogas via the anaerobic co-digestion of EFB under mesophilic anaerobic condition. The results revealed that subjecting EFB to an alkaline pretreatment method enabled a high-concentration methane yield. The raw biogas obtained from the anaerobic co-digestion of POME and EFB at 1.013 bar contained 61% CH4, 33.5% CO2 and 180 ppm H2S and was produced at rate of 51 - 68㎥/h. The utilization of biomethane as a bio-CNG gas has been unexplored: hence, this study investigated the purification of POME biogas into bio-CNG gas. The pretreatment of raw biogas using chelate-iron (EDTA-iron solution) process, which is the most promising technique for the removal of 99% H2S, was employed in this study. A pilot-scale separation plant with a capacity of 20㎥/hr that utilize cellulosic spiral wound membrane (MTR, USA) for upgrading biogas to CNG fuel quality was constructed and operated at the biogas plant. The result contained 99.1% CH4, 1.8% CO2, 0.004% H2O and 0.9 ppm H2S. These results indicate that the energy contents of biogas can be significantly enhanced by upgrading it to CNG fuel.

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