This study aims to derive the optimal condition that ensures the monolithicity of ultra-high performance concrete (UHPC), through the evaluation of bonding shear performance with respect to the time of cold joint occurrence during the placement. From the direct shear test, while the normalized bonding shear strength reduction of UHPC with the delay time of 15 minutes was the lowest at around 8%, a dramatic degradation of bonding shear performance was observed after 15 minutes. XRD analysis of the middle and surface sections was performed in order to analyze the composition of the thin film formed at the surface of UHPC, and as a result, the main ingredient appeared to be SiO2 from the XRD pattern of middle and surface sections, which is believed to be the result of the rising of SiO2-based filler, used as anadmixture in this study, toward the surface, due to its low specific gravity.