Present study was undertaken to investigate the effects of composition ratio and temperature on the friction and wear of PTFE-polyimide composites under the atmosphere of nitrogen gas. The load range was 0.62-3.46 MPa, and the temperature range was room temperature and 200$^{\circ}$C. To mention some of the notable results, friction coefficient of PTFE 100% varied relatively little within the given load and temperature ranges. Polyimide 100% showed the lowest friction coefficient of 0.06 at 200$^{\circ}$C among all the experiments. PTFE 80%-polyimide 20% showed the lowest wear factors on the whole. Friction coefficient of PTFE 20%-polyimide 80% varied from the highest 0.35 to the lowest 0.09 among all the materials at room temperature, and showed almost the same lowest values with polyimide 100% at 200$^{\circ}$C. Suggestion of friction and wear mechanisms of the materials was tried to explain the observed phenomena including above mentioned results.