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Indium assisted hydride vapor phase epitaxy of GaN film
Guanghui Yu, Benliang Lei, Haohua Ye, Sheng Meng, Ming Qi, Aizhen Li, Jun Chen, Gerard Nouet, JPierre Ruterana
UCI G704-001111.2006.7.2.009

Hydrogenated amorphous silicon (a-Si:H) and hydrogenated amorphous silicon carbide (a-SiC:H) films of different compositions were deposited by plasma enhanced chemical vapor deposition (PECVD). For a-Si:H thin films, we have investigated the effect of the rf power on the microstructural properties, such as crystal structure and crystallinity. A diffraction peak (Si (111)) positioned at about 2θ = 28° appeared from a thin film grown on a Si (100) substrate at rf power of 300 W, suggesting a local crystallization of the film. For a-SiC:H thin films, the predominant peak is ascribed to (200) of β-SiC structure, which confirms the formation of β-SiC upon 900 annealing. No peak corresponding to the (111) or (220) planes of β-SiC is detected, suggesting that the films might exist in a single crystalline state.

In order to increase the migration length of adatoms in hydride vapor phase epitaxy (HVPE) of GaN films, indium was used as a surfactant in HVPE growth. For samples with indium, an increase of crystalline quality was confirmed by X-ray diffraction measurements, and an improvement of surface morphology was also observed. SIMS analysis showed that indium was incorporated in the as-grown GaN film, and indium related photoluminescence (PL) was also detected.

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