Surface treatment and chemiluminescence characteristics of the polymer film. It was studied that the intensities and rates of treatments are in proportional to condition of the treatment, considering the results of study on treatments to polymer film with discharge and ultraviolet irradiation through the methods such as surface resistance, contact angle, dyeing method, surace tension and so on. It was also studied that the said has a nice correlation with the concerned result studied by chemiluminescence. Since the chemiluminescence will enable the investigators to grasp a eertain condition caused by quitely slight deterioration with high sensitivity, it can be also used as a way for getting an information regarding the decision for degradation-condition and life-estimating of insulation material basically related to some security matters as well as surface condition of treatments through the above method.