An efficient process for recovery of calcium from the eggshell was developed and some organic acids were used in an attempt to enhance the degree of calcium ionization. Eggshell membrane was readily separated from crushed eggshell based on the differences in specific gravities. The conditions which allowed most efficient membrane removal were found to be 30 rpm of speed, 30 min of residence time and 0.08 of volume fraction. It took 3 hours for the eggshell powder prepared at 1000℃ to reach L value of 90 with the Hausner ratio being 1.43. The calcium ion concentrations were 990, 3500, 3900 and 4200 ppm in pure water, acetic acid, citric acid and lactic acid(0.05∼3%) aqueous solution, respectively. The degrees of ionization of calcium-citrate-malate complex(CCM), calcium-citric acid complex(CC) and calcium malic acid complex(CM) increased by 4 to 5 times compared to eggshell calcium powder.