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216.73.216.143
216.73.216.143
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SCIE
항균성 , N - [ 1 - ( benzotriazol - 1 - yl ) benzyl ] aniline 의 가수분해 반응에 미치는 미셀 촉매효과
Micellar Catalysis on the Hydrolysis of the Fungicidal N - [ 1 - ( benzotriazol - 1 - yl ) benzyl ] aniline
성낙도(Nack Do Sung), 박천규(Cheon Kyu Park), 임치환(Chi Hwan Lim)
UCI I410-ECN-0102-2008-520-000740433

The hydrolysis of fungicidal N-[1-(benzotriazol-1-yl)benzyl]aniline (BBA) molecule in the presence of cationic cetyltrimethylammonium bromide (CTABr) and anionic sodium laurylsulfate (NaLs) micellar solutions has been studied kinetically. The Micellar catalysis effect shows that the rate is slightly accelerated by the addition of the anionic NaLs at high pH and the binding constant (Ks) is 1.45×10⁴ M^(-1). This result presumably is due to the electrostatic stabilization by the anionic micelle of the developing carbocation in the transition state rather than the hydrophobic character (π: 4.93) of (BBA).

[자료제공 : 네이버학술정보]
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