Carpenter bee pheromone 의 2 - methyl - 5 ( S ) - hexanolide 의 부분 입체선택적 합성

장재혁; 이상준; 김정한

한국응용생명화학회 한국응용생명화학회지 Carpenter bee pheromone 의 2 - methyl - 5 ( S ) - hexanolide 의 부분 입체선택적 합성

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The diastereoselective synthesis of 2 - methyl - 5 ( S ) - hexanolide

장재혁(Jay Hyok Chang), 이상준(Sang Jun Lee), 김정한(Jung Han Kim)

한국응용생명화학회 1994.02

한국응용생명화학회지 vol. 37 iss. 1 25-29(5pages)

UCI I410-ECN-0102-2008-520-000753467

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Abstract

2-methyl-5(S)-hexanolide(1); the major component of pheromonal blend of the male carpenter bee was synthesized via Homer-Emmons reaction from Ethyl(S)-3-hydroxybutyrate(2a) which had been obtained by Baker`s Yeast reduction in overall yield 39%.

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