This study investigated the concentration of Volatile Organic Compounds (VOCs) and identify the impact of associated meteorological factors in Songam Industrial Complex in Gwangju. Accordingly, we performed a factor analysis to estimate the source of VOCs emissions. Findings included a high level of toluene, acetone, butyl acetate, etc. within the Songam industrial complex, the atmospheric conditions near the proximity of the industrial complex and residential areas manifested a resembling trend. The atmosphere of the nearby environment is thought to be affected by VOCs emitted from the industrial complex. The weather factor analysis demonstrated that the distribution of the VOCs concentration affects the velocity of winds. Upon completion of the factor analysis in the industrial complex, the VOCs emissions in the industrial complex were induced by four factors, of which primary factors indicate painting facilities and exhaust gas of diesel vehicles. The factors of VOCs emissions in residential areas showed five, including the painting facilities and exhaust gas from diesel vehicles as primary factors, which is congruent with the factors in the industrial complex.