Various non-destructive test have been developed to predict the setting time of concrete. Through the electrical resistivity method(Wenner’s four electrode method), the effect of chemical admixture(AE admixture and superplasticizer) added for setting time of concrete mixtures is confirmed. As a result, it is observed that AE admixture dose not affect to change of concrete microstructure but delaying on setting time, and superplasticizer is affected not delaying on setting time, but changing in concrete’s microstructure.