The purpose of this study is to compare and analyze the effect of type and volume fraction of fiber on the electrical conductivity and shielding effectiveness of cementitious composites. The large specific surface area of amorphous metallic fiber, as well as the high number of fibers per unit weight, provided an advantage in the formation of conductive path. As the result, the electrical conductivity of amorphous metallic fiber was evaluated to be higher, and the shielding effectiveness was also higher. However, the shielding effectiveness according to electrical conductivity was confirmed to have a threshold point, and further research is needed to improve it.