This study aims to investigate the influence of the droplet volume on the evaporation characteristics of the sessile droplet. In particular, the effect of the free convection in the vapor domain on the evaporation rate was analyzed through the numerical simulation. The commercial code of the ANSYS Fluent (V.2020 R2) was used to simulate the heat transfer in the liquid-vapor domain. Moreover, we used the diffusion model to estimate the evaporation rate for the different droplet volume under the room temperature. It was found that the evaporation rate significantly increases with the droplet volume because of the larger surface area for the mass transfer. Also, the effect of free convection on the evaporation rate becomes significant with an increment of droplet volume owing to the increase in the droplet radius corresponding to the characteristic length of the free convection.