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Effects of loading change and promoters on V/MPTiO2 for Selective catalytic reduction of NO with NH3
전세원 , 송인학 , 이황호 , 김도희
UCI I410-ECN-0102-2019-500-001471341
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NH3-SCR is considered as an effectual NOx removal technique and in particular, vanadium based catalysts are often used in SCR. Vanadium based catalysts have broad operating temperature range and are strongly resistant to sulfur and its affordable price is also advantageous. Recently, microporous titania has been used as a promising support because of its noticeable benefits over the commercial titania (DT51). It obtains a larger surface area, 158.6 ㎡/g, than the commercial titania, 82.47 ㎡/g, restrains undesired product, N2O and has broad performance temperature range. Due to these advantages, the catalysts supported on MPTiO2 were expected to have higher NOx conversion in low temperature than on DT51. In the present study, different amounts of vanadium (3-10 wt%) and various promoters were loaded. Characterizations including NH3-TPD and H2-TPR were performed to investigate how the catalytic activity was effected by loading change and promoter effects.

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