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KCI 등재 SCOPUS
염전폐수 내 금속이온 농도변화에 따른 금속탄산염 생성량의 경향성 및 결정구조에 관한 연구
A Study on Tendency of Metal Carbonate Formation and Crystal Structures using Seawater-based Concentrated Wastewater
김인준 ( Injun Kim ) , 강동우 ( Dongwoo Kang ) , 유윤성 ( Yunsung Yoo ) , 김병환 ( Byung Hwan Kim ) , 박진원 ( Jinwon Park )
DOI 10.9786/kswm.2018.35.1.31
UCI I410-ECN-0102-2019-500-001515931

This study deals with inorganic Carbon dioxide Capture Utilization (CCU) by using seawater-based industrial wastewater. Industrial wastewater, which contains plenty of cations such as Ca2+ and Mg2+, is considered as a cation source for mineral carbonation. Modeled industrial wastewater was used to study the tendency of mineral carbonation on various condition. Cation concentration of industrial wastewater was modified at various levels and then reacted with fully CO2- absorbed 30wt.% monoethanolamine (MEA) solution. A metal carbonate precipitated as a result of the reaction, and the same experiment was performed with 1/3, 2/3 CO2-absorbed MEA solution to study the tendency of carbonation under different CO3 2- conditions. The amount of precipitate was increased proportionally to the cation concentration and the amount of absorbed CO2. Most of the precipitate was calcium carbonate (CaCO3), although other metal carbonates were also formed. Most of the CaCO3 was found in calcite form, but vaterite and aragonite were also formed under specific conditions. Based on the experimental results, we conclude that by controlling the concentration of cations and CO3 2-, we were able to optimize mineral carbonation conditions. We also noticed that low CO3 2- concentration in MEA solutions is advantageous for producing high quality calcium carbonate crystals. Inductively Coupled Plasma (ICP), X-ray Diffraction (XRD), and Scanning Electron Microscopy (SEM) analyses were performed to analyze the precipitate.

I. 서 론
II. 연구방법
III. 결과 및 고찰
IV. 결 론
사 사
References
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