Herein, we report industrially adoptable fluid dynamic exfoliation process to produce large quantities of ionic liquid (IL)-functionalized metallic phase MoS2 (m-MoS2) and defect-free graphene (Gr) sheets. We also fabricate hybrid 2D-2D layered films by incorporating Gr sheets into compact m-MoS2 films. The incorporated IL functionalities and Gr sheets prevent aggregation and restacking of the m-MoS2 sheets, thereby creating create efficient and rapid ion and electron pathways in the hybrid films.