Two different emitting compounds, 1-[1,1;3,1]Terphenyl-5-yl-6-(10-[1,1;3,1]terphenyl-5-ylanthracen-9-yl)-pyrene (TP-AP-TP) and Polyphenylene vinylene derivative (PDY 132) were used to white OLED device. By incorporating adjacent blue and yellow emitting layers in a multi-layered structure, highly efficient white emission has been attained. The device was fabricated with a hybrid configuration structure: ITO/PEDOT (40 nm)/PDY-132 (8∼50 nm)/ NPB (10 nm)/TP-AP-TP (30 nm)/Alq3 (20 nm)/LiF (1 nm)/Al (200 nm). After fixing TP-AP-TP thickness of 30 nm by evaporation, PDY-132 thickness varied with 8, 15, 35, and 50 nm by spin coating in device. The luminance efficiency of the white devices at 10 mA/cm2 were 2.93 cd/A∼6.55 cd/A. One of white devices showed 6.55 cd/A and white color of (0.290, 0.331).