In this research, owing to the development of industry and improvement of building techniques, concrete structures are becoming larger and higher. This study investigates the thermal properties of concrete according to several binder conditions, such as OPC, Belite rich cement, slag powder, limestone powder and flyash added cement. To investigate effects of PC type terpolymers on the hydration of cement, experiments involving FT-IR, XRD, DSC, SEM have been analysed with cement paste specimens to 1, 3, 28 day. The hydration reaction rate of cement paste was slightly delayed at 1day, due to increase in molar ratio of PC type. It is more effective to use mineral admixture. Especially, to be used blast furnace slag and fly ash added cement is more effective.