Graphene and its oxidized form of Graphene oxide have been of particular interest in material science due to their exceptional physical properties. However, relatively little attention has been paid to the GO dispersions although the state of dispersions directly affect to the material property. For example, GO can be well-dispersed in water due to their hydrophilic functionalities but, easily form gels or glass around 1 wt%, which often act as an obstacle in GO based composite production. Thus, to understand the structure and mechanism of GO dispersions is an essential step before moving to the application phase. In this study, we systematically study the GO dispersion at various conditions and examine how GO glass transition is affected by the presence of polymer. An intriguing observation was that adding polymer can effectively retard glass transition of GO in water. Extensive small angle x-ray scattering and rheological studies are employed to probe the GO structures.