Although the carbonation problem of high-volume slag concrete has been solved by the mixed use of emulsified refine cooling oil as the pilot study, there was an instance of securing air quantity and frost resistance followed by the use of Expancel due to the problem of having vulnerability in frost resistance in result as the air quantity has not been secured. But due to the problem of Expancel not being economical, air quantity and frost resistance of high-volume slag concrete mixed with ERCO are attempted to be secured using micro bubble that can remain in the water for a long time as a relatively economical and very microscopic bubble.