A mold of free-form concrete segment can be used only one time. Thus, the construction duration and cost are increased. The materials of the mold such as wood and metal have limitations due to the implementation and reuse. The review of the material of the mold for free-form concrete segment is needed to reduce duration and production cost. Phase change material can be used both to implement free-shape by heating and to produce mold after cooling. After using Phase change material can be re-used to mold by heating. The scope of this study is many kind of phase change materials for molding. The aim of this study is to analyze the phase change materials for production of changable mold for free-form concrete segment. In this study, the paraffin wax that is melted at 64 ℃ was selected by considering both the energy efficiency and the weather of Korea.