We have fabricated solar cell devices based on zinc-phthalocyanine(ZnPc) as donor(D) and fullerene(C60) as electron acceptor(A) with doped charge transport layers, and BCP and Alq3 as an exciton blocking layer(EBL). We have measured the photovoltaic characteristics of the solar cell devices using the Xe lamp as a light source. We were use of Alq3 layer leads to external power conversion efficiency was 2.65% at illumination intensity 100mW/㎠. Also we confirmed the optimum thickness ratio of the DA hetero-junction is about 1:2.