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Microbial transformation of the sweet sesquiterpene (+)-hernandulci
(Hyun Ju Yang),(Hyun Jung Kim),(Yun Ae Whang),(Jung Kap Choi),(Ik Soo Lee)
UCI I410-ECN-0102-2009-510-009545910
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(+)-Hernandulcin is a sweet bisabolane-type sesquiterpene first isolated from Lippia dulcis Trev. (Verbenaceae). This oily compound is 1000-1500 times sweeter than sucrose but with poor solubility in water. Microbial transformation was employed to improve its water solubility, and a variety of microorganisms were screened for their ability to convert (+)-hernandulcin to more polar metabolites. Scale-up fermentation with Glomerella cingulata, a fungal strain, has resulted in the isolation of a more polar metabolite (2).

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