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KCI 등재
커크우드-버프 용액 이론
Kirkwood-Buff Solution Theory
임경희 ( Kyung Hee Lim )
UCI I410-ECN-0102-2012-430-001682723
* 발행 기관의 요청으로 이용이 불가한 자료입니다.

Any theory of liquid should account for interactions between molecules, since molecules in a liquid are close to each other. For this matter statistical-mechanical methodology has been used and various models have been proposed on the basis of this methodology. Among them Kirkwood-Buff solution theory has attracted a lot of interest, because it is regarded as being the most powerful. In this article Kirkwood-Buff solution theory is revisited and its key equations are derived. On the way to these equations, the concepts of pair correlation function, radial distribution function, Kirkwood-Buff integration are explained and implemented. Since complexity of statical mechanics involved in this theory, the equations are applied to one-component systems and the results are compared to those obtained by classical thermodynamics. This may be a simple way for Kirkwood-Buff solution theory to be examined for its validity.

[자료제공 : 네이버학술정보]
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