닫기
216.73.216.191
216.73.216.191
close menu
KCI 등재
암모니움 이온을 가진 카드뮴 호스트 착물의 방향족 게스트 분자에 대한 포접선택성 변화
Variation of Inclusion Selectivities of the Cadmium Host Complexes with Ammonium Oniums for Aromatic Guest Molecules
김종혁 ( Chong Hyeak Kim ) , 이석근 ( Sueg Geun Lee )
분석과학 17권 3호 282-288(7pages)
UCI I410-ECN-0102-2009-430-002205263
* 발행 기관의 요청으로 이용이 불가한 자료입니다.

Inclusion selectivities of the cyanocadmate host complexes with ammonium oniums, [Cd_(x)(CN)_(2x)][onium zG] (onium = NMe₃Et^(+), NMeEt₃^(+) and NEt₄^(+), G = guest), have been investigated for C_(6)H_(6) (B), PhMe (T), PhEt (E), ortho (0), meta (M), and para (P) isomers of C_(6)H₄Me₂ as the aromatic guest molecules. From the binary, ternary, quaternary and quinary mixed guests of B, T, E, O, M and P, the order of preference in the NMe₃Et+-host is B》T>P≒O≒ M and E>0》P≒M; in the NMeEt₃^(+)-host is T>B>P》O≒M and E>P》M>O; in the NEt₄^(+)-host is B>TO=MP. However, the NEta`-host complexes of E, O, M and P mixed-guests were not obtained. These inclusion selectivities were compared to our previous results of the NMe₄^(+)-host; T>B>P》M>O and E>P》M>O.

[자료제공 : 네이버학술정보]
×