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2004년 화학공학회/공업화학회 공동 학술대회 논문집 : 망간지지체를 이용한 귀금속계 촉매의 선택적 CO 산화반응 연구
Proceedings of 2004 KIChE and KSIEC Meeting : Preferential Oxidation of Carbon Monoxide with Precious Metal Catalyst Supported by NMO(Natural Manganese Ore)
두강진 ( Kang Jin Doo ) , 차왕석 ( Wang Seog Cha ) , 박종수 ( Jong Soo Park ) , 조성호 ( Sung Ho Cho ) , 이근후 ( Keun Hoo Lee )
응용화학 8권 2호 681-684(4pages)
UCI I410-ECN-0102-2009-570-002457002
이 자료는 4페이지 이하의 자료입니다.

A preferential oxidation of CO remaining in reformed Hz fules(PROX) is one of the process to avoid a serious poisoning of anode-catalysts in fuel cells. Support screening studies have revealed NMO and alumina to be suitable for the prefernetial oxidation reaction within a temperature range of 130~230℃. The performance of a NMO supported 2.0wt% Pt and Rh catalyst for the oxidative removal of CO from H₂-rich methane reformate(1% CO, 65% H₂, 10% water) was investigated and compared to that of conventional catalysts In this paper, we present the results of selective CO oxidation in simulated reformate gas over Rh/NMO catalyst. The effect of water vapor, CO and oxygen concentration, temperature. and Rh loading on the activity and selectivity are presents. NMO appeared as a suitable support for the preferential CO oxidation catalyst at a wide temperature region.

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