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유연쇄를 사용한 개질 폴리에스터 공중합체의 제조와 그 특성(1) -BHPP [2,2-bis(4-(2-hydroxyethoxy) phenyl)] Propane-
Synthesis and Properties of Modified Copolyesters Containing Flexible Chain Moiety(1) -BHPP [2,2-bis(4-(2-hydroxyethoxy) phenyl)] Propane-
손태원 ( Tae Won Son ) , 박광현 ( Kwang Hun Park ) , 조진원 ( Jin Won Cho ) , 김영훈 ( Young Hun Kim ) , 최용혁 ( Yong Hyeok Choi )
UCI I410-ECN-0102-2009-580-002454070
* 발행 기관의 요청으로 구매가 불가능한 자료입니다.

Poly(ethylene terephthalate)(PET) was chemically modified through copolymerization of bis(2-hydroxyethyl) terephthalate (BHET) and 2.2-bis(4-(2-hydroxyethoxy) phenyl) propane (BHPP) as a flexible chain moiety to enhance high-speed spinnability by retarding the stress-induced crystallization during spinning. The properties of the copolyester were investigated using GPC, DSC(differential scanning calorimetry), TGA(thermogravimetry analysis), and proton-NMR. From the result of GPC, it was found that the copolyesters had higher molecular weight and narrower molecular weight distribution than those of PET obtained from BHET only. Non-isothermal crystallization measurement showed that T_(㎝)(melt-crystallization temperature) decreased and T_(cc)(cold crystallization temperature) increased with increasing amount of comonomer. It seems that the rate of crystallization of copolymer might be retarded during melt-spinning. Isothermal melt-crystallization measurement suggested that the rate of crystallization was lowered and Avrami index decreased with increasing amount of comonomer. However. incorporation of the comonomer did not affect the crystal structure of PET.

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