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사진식각법을 이용한 FET 형 용존 CO2 센서의 수화젤막 및 가스 투과막 제작
Fabrication of Hydrogel and Gas Permeable Membranes for FET Type Dissolved CO2 Sensor by Photolithographic Method
박이순 , 김상대 , 고광락 ( Lee Soon Park , Sang Tae Kim , Kwang nak Koh )
센서학회지 vol. 6 iss. 3 207-213(7pages)
UCI I410-ECN-0102-2008-530-001331650

ect transistor(FET) type dissolved carbon dioxide(pCO₂) sensor with a double layer structure of hydrogel membrane and CO₂ gas permeable membrane was fabricated by utilizing a H^+ ion selective field effect transister(pH-ISFET) with Ag/AgCl reference electrode as a base chip. Formation of hydrogel membrane with photo-crosslinkable PVA-SbQ or PVP-PVAc/photosensitizer system was not suitable with the photolithographic process. Furthermore, hydrogel membrane on pH-ISFET base chip could be fabricated by photolithographic method with the aid of N,N,N`,N`-tetramethyl ethylenediamine(TED) as O₂ quencher without using polyester film as a O₂ blanket during UV irradiation process. Photosensitive urethane acrylate type oligomer was used as gas permeable membrane on top of hydrogel layer. The FET type pCO₂ sensor fabricated by photolithographic method showed good linearity (linear calibration curve) in the range of 10^(-3)∼10 mole/ℓ of dissolved CO₂ in aqueous solution with high sensitivity.

[자료제공 : 네이버학술정보]
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