The evaluation of thermal and pressure hazard of chemicals on the manufacturing, transporting and storaging is important in the chemical industry for safety. In this study, the thermal decomposition characteristics of intermediate of Saccharin were investigated by using Accelerating Rate Calorimeter(ARC) and Differential Scanning Calorimeter(DSC). Experimental results showed that decomposition temperatures in p=TSA were about 280∼31 ℃ by DSC and 201℃ by ARC. In case of o-TSA were about 336℃∼360.8℃ by DSC and 299 ℃ by ARC. The decomposition temperature acquired by ARC was about 70℃ lower than that by DSC. The exothermic runaway reaction in case of p-TSA occured in 598 minute and o-TSA in 5 minute. For the safety in the chemical industry, we should consider the ARC data as well as DSC data in the handling and design of process.