Hazard and operability (HAZOP) analysis is one of the safety analysis method that is used in the chemical complex, because it can systematically identify causes and consequences of all the deviation that could occur. Since this method needs to hire specialized experts, it is costly and time-consuming. Therefore HAZOP Expert System has been developed to automate this analysis. This approach introduced object-oriented method and knowledge representation which is hierarchical tree of units to supply flexibility in the system, functional semantic network, propagation equation and rule-chaining method to set up the expert system for automating HAZOP analysis.