Demand of LPG and LNG will increase continuously due to high calories, clearness, and convenience for usage. These gases are used widely for power plants, industrial plants, and domestic fuel. But accidents related with gas are increasing in proportion to increment of gas usage. Especially, LPG has high ignitability due to weak dispersion to air and accumulation at low place because LPG is heavier than air. There are many hazards during transportation as well as production, storage, and usage of LPG. Commonly, tank lorry is used for inland transportation of LPG. If tank lorry were to raise leakage incidents and then LPG released during transporting, the accidents cause serious effects on the environment as well as human damage of surrounding area. In this study, therefore, hazards which cause LPG of tank lorry to leak during transportation were identified and risk of LPG transportation was assessed quantitatively. Also, the result of this study might be a useful measure for predicting damage and preparing safe transportation strategies of LPG tank lorry.