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가황시스템 변화가 가황고무의 점탄성적 특성에 미치는 효과
The Effect of Cure System for the Viscoelastic Properties of Vulcanized Rubber
이석(Seag Lee), 박남국(Nam Cook Park)
UCI I410-ECN-0102-2008-580-001212172

Rebound, storage and loss modulus, and tan δ were investigated on cured rubbers with various ratios of sulfur to accelerator and the volume fraction of carbon black in the cured rubbers. The rebound was increased as the sulfur to accelerator ratio and the volume fraction of carbon black decreased. The storage modulus decreased as the loading of carbon black and the strain increased regardless of the cure systems. The network structure formed by filler-filler interaction was destroyed above 6% strain regardless of the loading of carbon black, because constant storage modulus was shown at the higher strain than 3% for 40∼50 phr loading of carbon black and at the higher strain than 6% for 60 phr and above loading of carbon black. Little effect on loss modulus was found at the low loading of carbon black, but the peak of loss modulus was shown at 1% strain as the loading of carbon black was increased. Tan δ increased as the loading of carbon black and the strain were increased regardless of the cure system, and maximum tan δ was shown at 2% strain regardless of the loading of carbon black.

[자료제공 : 네이버학술정보]
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