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EPDM 계 열가소성 가황체의 형태학적 연구
Morphology of EPDM - based Thermoplastic Vulcanizate
이상진 , 김영규 , 박성수 , 조원제 , 하창식 ( Sang Jin Lee , Young Kyoo Kim , Seong Soo Park , Won Jei Cho , Chang Sik Ha )
UCI I410-ECN-0102-2008-580-001204618

The morphology of the thermoplastic vulcanizates prepared from ethylene-propylene-diene terpolymer, polypropylene and high density polyethylene(HDPE) or ethylene based ionomer were studied. Blends were prepared in a laboratory internal mixer where EPDM was cured in the presence of PP and HDPE or ionomer under shear with dicumyl peroxide(DCP). The effects of DCP concentration and rubber/plastics composition were studied. In the morphological analysis by scanning electron microscopy (SEM), a small amount of EPDM acted as a compatibilizer to HDPE and PP. It was also revealed that the dynamic vulcanization process could reduce the domain size of the crosslinked EPDM phase. When ionomer was added to EPDM/PP blend, the thermoplastic vulcanizate showed typical ductile fracture topology and the trend was more clearly observed when DCP contents and ionomer contents are higher.

[자료제공 : 네이버학술정보]
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