The Thermal decomposition of the α-Cellulose and NaCl was studied using a thermal analysis technique in the steam of nitrogen gas with 30㎖/min at various heating ranges from 4 to 20℃/min. The Derivative and Integral method used to be obtained values of activation energy of decomposition reaction. 1. The values of activation energy evaluated by Derivative and Intergral method were consistent with each other very well. 2. The maximum value of heat of decomposition evalated by DSC method was α-Cellulose/NaCl=90/10. 3. The thermogravimetric trace curve agreed with the theoretical equation.