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18.97.14.80
18.97.14.80
도전성 고무의 충전제로 이용 가능한 Dy2 - xSr1+xFe2O7 - y 페라이트계의 전기적 특성에 대한 연구
Studies on the Electrical Properties of dy2 - xSr1+xFe2O7 - y Ferrite System Which Can be used as Filler for Conducting Rubbers
이은석 , 최세영 ( Eun Seok Lee , Sei Young Choi )
UCI I410-ECN-0102-2008-580-001209411

To make new filler for conducting rubber, the sample of perovskite-related ferrite system Dy₂ _xSr_(1+x)Fe₂O_(7 y) (x=0.0, 0.5, 1.0, 1.5, and 2.0) were synthesized at 1473 K in air. Mo¨ssbauer spetrum of x=0.0 sample shows typical six line pattern with Mo¨ssbauer parameters, I.S.=3.6×10^(-1)㎜/sec, E_Q=-7.0×10^(-2)㎜/sec, H_(int)= 5.19×10² KOe. In case of x=2.0, the spectrum is composed of single line exhibiting coexistence of Fe^(3+)(I.S.=3.7×10^(-1)㎜/sec) ions and Fe^(4+)(I.S.=-1.9×10^(-1)㎜/sec) ions. With increase in x value electrical conductivity at constant temperature sharply increased and the activation energies decreased from 3.8×10^(-1) to 1.9×10^(-1) eV.

[자료제공 : 네이버학술정보]
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