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18.97.14.88
18.97.14.88
반응성노화방지제의 가황특성에 관한 연구
Studies on the Vulcanization Characteristics of Rubber - Bound Antioxidants
백남철 ( Nam Chul Paik )
UCI I410-ECN-0102-2008-580-001211862

The purpose of this dissertation is to study some of the vulcanization characteristics of rubber-bound antioxidants such as G-1. 〔N-(3-methacryloyloxy-2-hydroxypropyl)-N`-phenyl-p-phenylene diamine〕 and acryl, acrylamide & acrylester substituted hindered phenols. The influence of these antioxidants upon vulcanization characteristics in NR and SBR compounds in the presence of vulcanizing accelerators such as MSA, TT, DM, M & D was evaluated by means of Oscillationg Disk Cure Meter. The comparison was also made between the influence of rubber-bound antioxidants and that of conventional non-reactive antioxidants such as N-alkyl substituted PADA series. Regarding the influence of reactive type antioxidant G-1 mixed with accelerator TT upon vulcanization characteristics, rapid onset of vulcanization and higher degree of cross-linking were discovered, whereas in the case of accelerator M and DM, the result was slow onset of vulcanization and lesser degree of cross-linking. The comparison of vulcanizing characteristics among acrylic substituted hindered phenols as antioxidants was made under several vulcanization accelerator systems. Under such systems, MSA-S combined accelerator caused the onset of vulcanization to slow down and lowered the degree of cross linking. Finally in the case of hindered phenol derivatives containing longer substituent, the delayed onset of vulcanization and the lowered degree of cross-linking could be discerned.

[자료제공 : 네이버학술정보]
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