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Research Articles : Electrochemical Oscillations in the HCHO Oxidation on a Pt Electrode
( In Hwa Jung ) , ( Do Yeon Kim ) , ( Jae Young Lee ) , ( In Hwan Oh ) , ( Heung Yong Ha ) , ( Yong Sug Tak )
UCI I410-ECN-0102-2009-570-003883906
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We first report that current oscillations with in-situ mass oscillations in the electrocatalytic oxidation of formaldehyde were observed on a Pt electrode. In the linear sweep voltammogram, quantitative analysis of in-situ mass change on the Pt surface by electrochemical quartz crystal microbalance gave a clue that CO migllt be the reaction intermediate species, which covered the active area of Pt surface. It results in the lowest current and the highest mass in a period of oscillations. On the other hand, the lowest value of mass arises from the recover of Pt vacant site due to the CO₂evolution. The periodicity of current oscillations is in excellent agreement with the mass oscillations.

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