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니켈촉매를 이용한 메탄의 부분산화에 의한 합성가스 제조
Partial Oxidation of Methane to Synthesis Gas over Ni Catalysts
함현식 ( Hyun Sik Hahm ) , 김상범 ( Sang Bum Kim ) , 신기석 ( Ki Seok Shin ) , 박은석 ( Eun Seok Park ) , 곽윤철 ( Yun Cheol Kwak ) , 천한진 ( Han Jin Cheon )
응용화학 6권 2호 843-846(4pages)
UCI I410-ECN-0102-2009-570-003885324
이 자료는 4페이지 이하의 자료입니다.

Synthesis gas was produced by the partial oxidation of methane with using supported 10~15 wt% Ni catalysts. The highest catalytic activity was obtained with MgO support when Ni loading was 13 wt%. With the 13 wt% Ni/MgO catalyst, methane conversion was 80%, and CO and H_2 selectivities were 93% and 94%, respectively. The activity of the catalyst remained nearly constant after 180 h of the reaction. To investigate the arguing reaction mechanism of this reaction, the temperature of the catalyst bed at top and bottom of the bed were measured with pulses of the reactants (CH_4:O_2 = 2:1); the changes in the moles of the reactants and products were tested with time; and O_2-TPD experiment was carried out. As a result, it is found that the reaction takes place by a two-step reaction - first, total oxidation of methane to CO_2 and H_2O takes place, and then the produced CO_2 and H_2O are further reacted with CH_4 to give synthesis gas.

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