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KCI 등재 SCOPUS
반응염료염액에서의 키틴의 염료흡착성능
Transactions : Dye Adsorption Ability of Chitin in Reactive Dyebath
이혜자(Hye Ja Lee),유혜자(Hye Ja Yoo),이전숙(Jeon Sook Rhie),김정희(Jung Hee Kim)
UCI I410-ECN-0102-2009-590-004487520

In order to decolorize the reactive dye wastewater, we investigated the dye-adsorption ability of chitin, which was natural polymer obtained from shrimp shell. Chitin particle(less than 25μm) was prepared from shrimp shells in the processes of decalcification in aqueous hydrochloric acid solution and deproteination in aqueous sodium hydroxide solution. The particle size of chitin was controlled to less than 25μm. Three types of the reactive dyes-C.I. Reactive Red 120, C.I. Reactive red 241 and CL Reactive Black 5-were used. Dye adsorption ability of chitin was investigated by dipping the particle in the dyebaths of concentration of 0.01%, 0.03% and 0.05% for various periods of time(1, 3, 5, 10, 20, 40, 80, 160minutes). The influence of addition of salt(Na_2SO_4) and alkali to the dyebaths on dye-absorption was also investigated. We obtained the following results for the dye-absorption ability of chitin in the dyebaths of three types of reactive dyes. 1) The amount of dye uptake by chitin was increased by addition of salt to the dyebaths. 2) As the concentration of alkali became higher than 3g/l, the amount of dye uptake by chitin was increased. Chitin showed good dye-adsorption ability, when the alkali concentration was high. 3) Chitin showed equal dye uptake in the three types of dyebaths when the dye concentration was 0.01%. Over 90% of dyestuffs was adsorbed from the dyebaths in ten minutes. When the dye concentration was higher, better adsorption ability was showed in a dye bath of Reactive black 5 than in the others. When the dye concentration was 0.03%, 90% of Reactive red 120 and Reactive red 241 was adsorbed in 40 minutes and the same of Reactive black 5 in 10 minutes. When the dye concentration was 0.05%, 90% of Reactive red 120 was adsorbed in 80 minutes, and Reactive black 5 in 10 minutes.

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