본 연구는 이산화탄소와 phenyl glycidyl ether(PGE)의 부가반응에 대한 속도론적 고찰에 관한 것이다. NaI와 폴리에틸렌글리콜(PEG-4000)의 혼합물을 촉매로 사용하여 고압반응기에서 반응실험을 수행하였다. 이산화탄소의 압력변화를 관찰함으로써 실시한 속도론적 고찰에서 반응속도는 PGE와 CO₂의 농도에 대하여 각각 1차 반응이었고, Henry 상수 H´=7.4×10^(-4) ㏖/ℓ·㎪로 나타났으며, 반응속도 상수 k=0.334 ℓ/㏖·min이었다

A kinetic study on the addition reaction of carbon dioxide and phenyl glycidyl ether(PGE) was investigated. NaI and polyethylene glycol(PEG-4000) was used as mixed catalyst, and the reaction was carried out using autoclave. A method to calculate rate constant and Henry`s law constant of CO₂ was proposed by measuring CO₂ pressure. The reaction was first order to the concentration of PGE and CO₂ respectively. The reaction rate constant(k) was 0.334 ℓ/㏖·min and Henry`s constant(H´) was 7.4×10^(-4) ㏖/ℓ·㎪.