PbTiO₃ 미립자를 수열합성하였다. 본 연구에서 출발물질은 PbO와 TiO₂의 화학양론적으로 혼합하였다. 단상으로 PbTiO₃를 합성하는데 KOH와 NaOH 용액이 가장 효과적이었다. 수열조건은 다음과 같다. : 즉, 온도 ; 250∼270℃, 유지시간 ; 10시간, 수열용매 ; 8M KOH 또는 NaOH 용액. 이들 입자들은 각각 KOH 용액에서 판상의, NaOH 용액에서 주상의 결정상으로 잘 발달하였다. 수열적으로 얻은 PbTiO₃입자 특성을 조사하여 다음 결과들을 얻었다. Pb/Ti 몰비 ; 약 1, 비표면적 ; KOH 경우 2.27∼2.43㎡/g, NaOH에서 4.74∼5.59㎡/g, 격자상수 ; a=0.390, c=0.414㎚(c/a=1.06), 큐리점 ; 약 470℃.

Synthesis of PbTiO₃ particles was carried out by the hydrothermal method. In this study, the starting powder was derived from a stoichiometric mixture of PbO and TiO₂ powders. KOH and NaOH solution was found to be the most effective solvent to synthesize PbTiO₃ particles as a single phase. The hydrothermal conditions for the synthesis of PbTiO₃ particles are as follows : temperature ; 250∼270℃, run duration ; 10hrs, hydrothermal solvent ; 8M KOH or NaOH solutions. These particles were of well developed crystalline PbTiO₃ with plate-like shape in KOH solution and acicular shape in NaOH solution, respectively. Characteristics of the hydrothermally obtained PbTiO₃ particles were investigated. And the following results were obtained : Pb/Ti mole ratio ; about 1, specific surface area ; 2.27∼2.43㎡/g in KOH solution and 4.74∼5.59㎡/g in NaOH solution, lattice constants ; a=0.390 and 0.414㎚(c/a=1.06), curie temperature about 470℃.