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Dichloroisocyanuric Acid Sodium Salt 에 의한 p - Nitrophenyl Diphenyl Phosphate 의 가수분해 반응
Hydrolysis of p - Nitrophenyldiphenylphosphate by Dichloroisocyanuric Acid Sodium Salt
이용한 , 박훈 , 최귀남 , 장성일 , 김태흥 ( Yong Han Lee , Hoon Park , Kui Nam Choi , Sung Il Chang , Tae Heung Kim )
공업화학 vol. 5 iss. 1 114-120(7pages)
UCI I410-ECN-0102-2009-570-007310017

DCI(dichloroisocyanuric acid sodium salt)에 의한 PNPDPP (p-nitrophenyldiphenylphosphate)의 미셀 내에서의 분해 반응을 pH 8.0 borate 완충용액에서 속도론적으로 살펴보았다. 양이온성 계면활성제인 CTAC (cetyl-trimethylammonium chloride) 또는 CTAB (cetyltrimethylammonium bromide)를 첨가하면 반응은 빠르게 촉진되었으며, 특히 CTAB의 경우는 DCI의 N-Cl 결합이 N-Br 결합으로 전환되어 반응이 진행되었다.

Esterolysis reactions of PNPDPP (p-nitrophenyldiphenylphosphate) by DCI (dichloroisocyanuric acid sodium salt) in borate buffer pH 8.0 micellar phase were studied. The rate of the hydrolysis reaction was rapidly increased by adding cationic surfactants, CTAC (cetyltrimethylammonium chloride) or CTAB (cetyltrimethylammonium bromide), to the DCI solution. Especially in CTAB micellar system, the N-Cl bond of DCI was transformed to the N-Br bond during the reaction.

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