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충전재 - 탄성체 상호작용 . 2. 카본블랙 / 고무 복합재료의 경화 거동 및 기계적 계면 물성
Filler - Elastomer Interactions . 2. Cure Behaviors and Mechanical Interfacial Properties of Carbon Black / Rubber Composites
박수진(Soo Jin Park),김정순(Jeong Soo Kim)
UCI I410-ECN-0102-2009-580-005876252

In this work, the effect of chemical surface treatments on morphology of carbon blacks was investigated in terms of cure behavior and tearing energy (G_r) of carbon blacks/rubber composites. As experimental results, the polar or nonpolar chemical treatment led to a significant physical change of carbon black morphology. The cure activation energies (E_a) and frequency factor (A) obtained from Kissinger equation decreased with improving the dispersion of carbon blacks, resulting in high reactivity. However, a significant advantage of carbon black/rubber composites is gained by carbon blacks treated in basic (BCB) or nonpolar (NCB) chemical solution, resulting in increasing the tearing energy. These results could be explained by changes of dispersion, agglomerate, surface functional group, void volume, and cross-linking density of carbon black/rubber composites.

[자료제공 : 네이버학술정보]
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