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고분자량 스티렌 - 부타디엔 고무와 저분자량 스티렌 - 부타디엔 고무 혼합물의 가황과 기계적 물성
Vulcanization and Mechanical Properties of High Molecular Weight Styrene - Butadiene Rubber / Low Molecular Weight Styrene - Butadiene Rubber Mixtures
이화우(Hwa Woo Lee),이대수(Dai Soo Lee),김병철(Byeong Cheol Kim),홍석표(Suk Pyo Hong)
UCI I410-ECN-0102-2009-580-007918884

Characteristics of high molecular weight styrene-butadiene rubber(HM-SBR)/low molecular weight styrene-butadiene rubber(LM-SBR) mixtures were studied to investigate how to modify the processability and the mechanical properties of styrene-butadiene rubber (SBR). Mooney viscosity of the HM-SBR/LM-SBR mixtures and torque increase due to the vulcanization decreased by increasing the LM-SBR content of the mixtures. Shore A hardness and rebound properties were decreased by increasing the LM-SBR content of the mixtures. It was found that the value of tan δ of the mixtures in rubbery state was increased, while glass transition temperatures of the vulcanized blends were constant by increasing the LM-SBR content of the mixtures. It was postulated that the decrease of Mooney viscosity by increasing the LMSBR content of the blends was due to plasticizing effects of the LM-SBR and the increased polydispersity of the mixtures. Change of mechanical properties of the vulcanized HM-SBR/LM-SBR mixtures was attributed to the decreased crosslink densities of the mixtures by increasing the LM-SBR content of the mixtures.

[자료제공 : 네이버학술정보]
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