This develops a new and advanced S/S knitwear material made of linen/bamboo blended yarn. Linen/bamboo knitted fabrics were compared with linen/polyester knitted fabrics in terms of appearance as well as physical and comfort properties. Rib knitted fabrics were remarkably thicker than plain knitted fabrics. Knitted fabrics based on polyester yarns were heavier than those based on bamboo yarn. The porosity decreased in the following order: linen 100% > bamboo 100% > polyester 100%. The drape properties of bamboo 100% and linen/bamboo knitted fabrics were excellent. The pilling resistances of linen 100% and linen/bamboo knitted fabrics were excellent. The highest and lowest air permeability was observed in the case of linen/bamboo knitted fabrics and polyester 100% knitted fabrics, respectively. The instant cool-feeling was enhanced as the bamboo yarns were blended. The thermal conductivity of linen 100% knitted fabrics was the highest and the thermal conductivity of linen/bamboo knitted fabrics was higher than linen/polyester knitted fabrics. Bamboo 100% knitted fabrics showed a higher moisture regain than polyester 100% knitted fabrics. The results confirmed the superior appearance and comfort of a novel S/S knit wear material made of linen/bamboo knitted fabric.